Command Line Kung Fu
Here is a bunch of commands that are good to bear in mind when you troubleshoot a Windows system. By knowing these you can find out a lot of information without depending on 3rd party applications.
arp -a
Find other systems on the same subnet that the machine has been communicating with lately.
ipconfig /displaydns
Useful to find out which other systems the machine have resolved using DNS.
net use \\[targetIP] [password] /u:[user]
Set up an SMB session. If you do not enter a password, you will be prompted for one.
net use * \\[targetIP]\[share] [password] /u:[user]
Mount a share on a target. Some versions of windows require you to enter the machine name before the username.
net use * \\[targetIP]\[share] [password] /u:[MachineName]\[user]